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Case Study 3: Photolysis of Terbufos Authors: Sarunya Hengpraprom and Cindy Lee, Environmental Engineering and Science, Clemson University. Abstract : This case study considers the rate at which exposure to sunlight can transform a pesticide known as terbufos. Transformation of a contaminant by photolysis will change its behavior in a given situation. In some cases, a product of photolysis is just as toxic or more toxic than the parent compound. In other cases, the products of photolysis are rendered nontoxic and the transformation can be considered beneficial. The experiment described in this case study produced some of the first basic kinetics data available to evaluate the importance of photolysis as a process to remove terbufos from the environment. For more detailed information about this research, see Lee, C. M.; Anderson, B.; and Elzerman, A. W. 1999. Photochemical oxidation of terbufos. Environmental Toxicology and Chemistry. 18(7):1349-1353. For further detail choose the appropriate section References 2. Nowell LH and Resek EA. 1994, Summary of national standards and guidelines for pesticides in water, bed sediment, and aquatic organisms and their applications to water-quality assessments: U.S. Geological Survey Open-File Report 94-44. 3. U.S. Environmental Protection Agency. 1988. Pesticide Fact Sheet Number 5.2: Terbufos. Office of Pesticide and Toxic Substances, Washington, DC, 1988.5-10 4. Mayer FL and Ellersieck MR. 1986. Manual of Acute Toxicity: Interpretation and Data Base for 410 Chemicals and 66 Species of Freshwater Animals. Resource Publication 160. U.S. Department of Interior, Fish and Wildlife Service, Washington, DC, 5-73. 5. Bascietto J. (EPA Hazard Evaluation Division). [Memo to M. Mantz]; Oct. 1987. Terbufos registration standard. 6. Extension Toxicology Network. 1996. Pesticide information profile: terbufos. 7. Spectrum laboratories. 1996. Chemical fact sheet: CAS # 13071799. 8. Felsot A, Wei L and Wilson J. 1982. Environmental chemodynamic studies with terbufos ("Counter") insecticide in soil under laboratory and field conditions. J. Environ. Sci. Health. B 17(6): 649-673. 9. Chapman RA and Harris CR. 1980. Insecticidal activity and persistence of terbufos, terbufos sulfoxide, and terbufos sulfone in soil. J Econ Entomol. 73: 536-543. 10. U.S. Environmental Protection Agency. 1988. Health Advisory: Terbufos. Office of Drinking Water, Washington, DC, 5-102 11. Turro NJ. 1978. Modern molecular photochemistry. Menlo Park, CA: Benjamin/Cummings Publishing Co. 12. Gray WV and Stephen JD. 2000. Environmental Chemistry. Oxford University Press Inc., New York. USA. 13. Schwarzenbach RP, Gschwend PM, Imoden DM. 1993. Environmental Organic Chemistry. New York: Wiley and Sons. 14. Zepp RG. 1980. Assessing the photochemistry of organic pollutants in aquatic environments: in Hague, ed. Dynamics, Exposure, and Hazard Assessment of toxic chemicals. Ann Arbor, MI. 15. U.S. Environmental Protection Agency. 1985. |
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